High-Energy Room-Temperature Sodium–Sulfur and
We elucidate the Na storage mechanisms and improvement strategies for battery performance. In particular, we discuss the advances in the development of battery
A sodium–sulfur (NaS) battery is a type of molten-salt battery that uses liquid sodium and liquid sulfur electrodes. This type of battery has a similar energy density to lithium-ion batteries, and is fabricated from inexpensive and low-toxicity materials.
Rechargeable room-temperature sodium–sulfur (Na–S) and sodium–selenium (Na–Se) batteries are gaining extensive attention for potential large-scale energy storage applications owing to their low cost and high theoretical energy density.
High-temperature sodium–sulfur (HT Na–S) batteries were first developed for electric vehicle (EV) applications due to their high theoretical volumetric energy density. In 1968, Kummer et al. from Ford Motor Company first released the details of the HT Na–S battery system using a β″-alumina solid electrolyte .
Despite their very low capital cost and high energy density (300-400 Wh/L), molten sodium–sulfur batteries have not achieved a wide-scale deployment yet compared to lithium-ion batteries: there have been ca. 200 installations, with a combined energy of 5 GWh and power of 0.72 GW, worldwide. vs. 948 GWh for lithium-ion batteries.
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